Recent Submissions

Article

Shielding Effects Provide a Dominant Mechanism in J-Aggregation-Induced Photoluminescence Enhancement of Carbon Nanotubes

(American Chemical Society (ACS), 2024-03-26) Piwonski, Hubert Marek; Szczepski, Kacper; Jaremko, Mariusz; Jaremko, Lukasz; Habuchi, Satoshi; Biological, Environmental Sciences and Engineering; Biological and Environmental Science and Engineering (BESE) Division; Bioscience; Bioscience Program

The unique photophysical properties of single-walled carbon nanotubes (SWCNTs) exhibit great potential for bioimaging applications. This led to extensive exploration of photosensitization methods to improve their faint shortwave infrared (SWIR) photoluminescence. Here, we report the mechanisms of SWCNT-assisted J-aggregation of cyanine dyes and the associated photoluminescence enhancement of SWCNTs in the SWIR spectral region. Surprisingly, we found that excitation energy transfer between the cyanine dyes and SWCNTs makes a negligible contribution to the overall photoluminescence enhancement. Instead, the shielding of SWCNTs from the surrounding water molecules through hydrogen bond-assisted macromolecular reorganization of ionic surfactants triggered by counterions and the physisorption of the dye molecules on the side walls of SWCNTs play a primary role in the photoluminescence enhancement of SWCNTs. We observed 2 orders of magnitude photoluminescence enhancement of SWCNTs by optimizing these factors. Our findings suggest that the proper shielding of SWCNTs is the critical factor for their photoluminescence enhancement, which has important implications for their application as imaging agents in biological settings.

Article

Suppressing Dielectric Loss in MXene/Polymer Nanocomposites through Interfacial Interactions

(American Chemical Society (ACS), 2024-03-25) Tu, Shaobo; Qiu, Longguo; Liu, Chen; Zeng, Fanshuai; Yuan, You-You; Hedhili, Mohamed N.; Musteata, Valentina-Elena; Ma, Yinchang; Liang, Kun; Jiang, Naisheng; Alshareef, Husam N.; Zhang, Xixiang; Applied Physics; Physical Sciences and Engineering; Physical Science and Engineering (PSE) Division; Surface Science; Electron Microscopy; Material Science and Engineering; Material Science and Engineering Program; School of Physics and Materials Science, Nanchang University, 999 Xuefu Road, Honggutan District, Nanchang, Jiangxi 330031, China; Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications, Ningbo Key Laboratory of Special Energy Materials and Chemistry, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China; School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

Although numerous polymer-based composites exhibit excellent dielectric permittivity, their dielectric performance in various applications is severely hampered by high dielectric loss induced by interfacial space charging and a leakage current. Herein, we demonstrate that embedding molten salt etched MXene into a poly(vinylidene fluoride–trifluoroethylene–chlorofluoroethylene) (P(VDF–TrFE–CFE))/poly(methyl methacrylate) (PMMA) hybrid matrix induces strong interfacial interactions, forming a close-packed inner polymer layer and leading to significantly suppressed dielectric loss and markedly increased dielectric permittivity over a broad frequency range. The intensive molecular interaction caused by the dense electronegative functional terminations (−O and −Cl) in MXene results in restricted polymer chain movement and dense molecular arrangement, which reduce the transportation of the mobile charge carriers. Consequently, compared to the neat polymer, the dielectric constant of the composite with 2.8 wt % MXene filler increases from ∼52 to ∼180 and the dielectric loss remains at the same value (∼0.06) at 1 kHz. We demonstrate that the dielectric loss suppression is largely due to the formation of close-packed interfaces between the MXene and the polymer matrix.

Article

Advancing high-performance visible light communication with long-wavelength InGaN-based micro-LEDs

(Springer Science and Business Media LLC, 2024-03-25) Hsiao, Fu-He; Miao, Wen-Chien; Lee, Tzu-Yi; Pai, Yi-Hua; Hung, Yu-Ying; Iida, Daisuke; Lin, Chun-Liang; Chow, Chi-Wai; Lin, Gong-Ru; Ohkawa, Kazuhiro; Kuo, Hao-Chung; Hong, Yu-Heng; Computer, Electrical and Mathematical Sciences and Engineering; Computer, Electrical and Mathematical Science and Engineering (CEMSE) Division; Electrical and Computer Engineering; Electrical and Computer Engineering Program

This study showcases a method for achieving high-performance yellow and red micro-LEDs through precise control of indium content within quantum wells. By employing a hybrid quantum well structure with our six core technologies, we can accomplish outstanding external quantum efficiency (EQE) and robust stripe bandwidth. The resulting 30 μm × 8 micro-LED arrays exhibit maximum EQE values of 11.56% and 5.47% for yellow and red variants, respectively. Notably, the yellow micro-LED arrays achieve data rates exceeding 1 Gbit/s for non-return-to-zero on–off keying (NRZ-OOK) format and 1.5 Gbit/s for orthogonal frequency-division multiplexing (OFDM) format. These findings underscore the significant potential of long-wavelength InGaN-based micro-LEDs, positioning them as highly promising candidates for both full-color microdisplays and visible light communication applications.

Article

Interfacial Properties of the Nitrogen + Water System in the Presence of Hydrophilic Silica

(American Chemical Society (ACS), 2024-03-20) Yao, Xinyu; Nair, Arun Kumar Narayanan; Che Ruslan, Mohd Fuad Anwari; Yang, Yafan; Yan, Bicheng; Lau, Denvid; Sun, Shuyu; Earth Science and Engineering; Physical Sciences and Engineering; Energy Resources and Petroleum Engineering; Ali I. Al-Naimi Petroleum Engineering Research Center; State Key Laboratory for Geomechanics and Deep Underground Engineering, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China; Department of Architecture and Civil Engineering, City University of Hong Kong, Hong Kong 999077, China

The interfacial properties of the N2 + H2O and N2 + H2O + silica systems were investigated (in the temperature range of 313–448 K and at pressures up to 50 MPa) by using extensive molecular dynamics simulations. The simulated interfacial tension (IFT) of the N2 + H2O system is in line with our density gradient theory predictions based on the cubic-plus-association equation of state and experimental data. These IFTs decrease with increasing pressure and temperature. The effects of pressure on these IFTs are less pronounced at high temperature. Here, the positive surface excess of N2 explains the decreasing behavior of the IFT as a function of pressure. It can be seen that the surface excess of N2 is reduced as the temperature is raised. This explains the less pronounced effects of the pressure on the IFTs at high temperature. The simulated water contact angle (CA) of the N2 + water + silica system is in the range of 38.6–54.5°. An important finding is that under the studied conditions, these water CAs are not strongly influenced by temperature and pressure. Here we find that the effects of the IFT between H2O and N2 are more pronounced on the adhesion tensions. The IFT between silica and H2O is found to be much lower than that between silica and N2 under all conditions. Negligible amounts of N2 were found to be adsorbed at the interface between the droplet and the silica surface. The relatively higher capillary pressure of the N2 + H2O + silica system indicates that the presence of N2 might be useful for the storage of CO2 in saline aquifers.

Article

3D-Printed Smartwatch Fabricated via Vat Photopolymerization for UV and Temperature Sensing Applications

(American Chemical Society (ACS), 2024-03-20) Alam, Fahad; Alsharif, Aljawharah A.; AlModaf, Fhad; Elatab, Nazek; Electrical and Computer Engineering; Computer, Electrical and Mathematical Sciences and Engineering; Mechanical Engineering; Physical Sciences and Engineering; Materials Science and Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia

Ultraviolet (UV) exposure overdose can cause health issues such as skin burns or other skin damage. In this work, a UV and temperature sensor smartwatch is developed, utilizing a multimaterial 3D printing approach via a vat photopolymerization–digital light processing technique. Photochromic (PC) pigments with different UV sensitivities, UVA (315–400 nm) and UVB (315–280 nm), were utilized to cover a wider range of UV exposure and were mixed in transparent resin, whereas the smartwatch was printed with controlled thickness gradients. A multifunctional sensor was next fabricated by adding a thermochromic (TC) material to PC, which is capable of sensing UV and temperature change. Colorimetric measurements assisted by a smartphone-based application provided instantaneous as well as cumulative UV exposure from sunlight. The mechanical properties of the device were also measured to determine its durability. The prototype of the wearable watch was prepared by fixing the 3D-printed dial to a commercially available silicon wristband suitable for all age groups. The 3D-printed watch is water-resistant and easily removable, allowing for its utilization in multiple outdoor activities. Thus, the developed wearable UV sensor alerts the user to the extent of their UV exposure, which can help protect them against overexposure.