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  • Composite nanofiltration membrane comprising one-dimensional erdite, two-dimensional reduced graphene oxide, and silkworm pupae binder

    Balaji, K.R.; Hardian, Rifan; Dileep Kumar, V.G.; Viswanatha, R.; Kumar, Suneel; Kumar, Surender; Singh, Archana; Santosh, Mysore Sridhar; Szekely, Gyorgy (Materials Today Chemistry, Elsevier, 2021-10-23) [Article]
    Composite nanofiltration membranes offer advantages because of synergetic effects among the constituent materials’ properties. However, the sustainability of both the membrane fabrication and the raw materials has been a drawback of this energy-efficient separation technology. We report the facile fabrication of a nanocomposite membrane composed of a two-dimensional (2D) material of reduced graphene oxide (rGO) combined with a one-dimensional (1D) material of a ternary metal-based chalcogenide (NaFeS2 or NFS), using silkworm pupae protein as a natural binder. All the source materials can be derived from either nature or waste, ensuring the sustainability of the membrane and its production method. The structural characteristics of the synthesized membranes were analyzed, and the morphology of the composite membranes was studied thoroughly. Thermogravimetric analysis, differential scanning calorimetry, and nanoindentation characterizations indicated that the composite membranes were mechanically and thermally stable. The water and acetone fluxes; salt, dye, and pollutant rejections; and long-term membrane performance were evaluated using a cross-flow filtration system. Solute rejection was observed to increase (up to 98%, 94%, 95%, and 78% for Rhodamine B, 2,4-dichlorophenol, MgCl2, and NaCl, respectively) with increasing concentration of the nanomaterials in the membrane. The fine-tuning of the molecular weight cut-off from 794 to 600 g mol–1 was achieved by varying the concentration of the nanomaterials from 1 to 3 mg mL–1 . Our research findings demonstrate the synergetic effects of combining 1D and 2D materials using silkworm pupae binder. The composite membrane was stable in different classes of organic solvents, including hydrocarbons, alcohols, esters, ethers, polar aprotic solvents, halogenated solvents, and ketones. This first use of natural pupae binder in constructing membrane materials paves the way toward the development of more sustainable membranes.
  • Deep characterization of paired chromatin and transcriptomes in four immune cell types from multiple sclerosis patients

    Fernandes, Sunjay Jude; Ericsson, Matilda; Khademi, Mohsen; Jagodic, Maja; Olsson, Tomas; Gomez-Cabrero, David; Kockum, Ingrid; Tegner, Jesper (Epigenomics, Future Medicine Ltd, 2021-10-22) [Article]
    Background: The putative involvement of chromatin states in multiple sclerosis (MS) is thus far unclear. Here we determined the association of chromatin-accessibility with concurrent genetic, epigenetic and transcriptional events. Material & methods: We generated paired assay for transposase-accessible chromatin sequencing and RNA-seq profiles from sorted blood immune CD4$^{+}$ and CD8$^{+}$ T cells, CD14$^{+}$ monocytes and CD19$^{+}$ B cells from healthy controls (HCs) and MS patients. Results: We identified differentially accessible regions between MS and HCs, primarily in CD4$^{+}$ and CD19$^{+}$. CD4$^{+}$ regions were enriched for MS-associated single nucleotide polymorphisms and differentially methylated loci. In the vicinity of differentially accessible regions of CD4$^{+}$ cells, 42 differentially expressed genes were identified. The top two dysregulated genes identified in this multilayer analysis were CCDC114 and SERTAD1. Conclusion: These findings provide new insight into the primary role of CD4$^{+}$ and CD19$^{+}$ cells in MS.
  • Optical diagnostics and multi-point pressure sensing on the knocking combustion with multiple spark ignition

    Shi, Hao; Tang, Qinglong; Uddeen, Kalim; Magnotti, Gaetano; Turner, James W. G. (Combustion and Flame, Elsevier BV, 2021-10-22) [Article]
    Engine knock is an abnormal combustion phenomenon that limits the thermal efficiency and service life of spark-ignition engines. A better understanding of the knock mechanisms and characteristics is beneficial to knock alleviation and engine efficiency improvement. In this study, a metal liner with four evenly-spaced spark plugs in the periphery of the combustion chamber is designed to initiate knock from different positions. Four spark strategies are applied to the single-cylinder optical research engine and six pressure sensors are utilized to analyze the local pressure oscillations in the cylinder. The knocking combustion is investigated by simultaneous 72 kHz high-speed imaging and 6-point pressure sensing. The experimental results indicate that using multiple spark-ignition could promote knock intensity, advance the start of auto-ignition and introduce more acoustic resonance modes. The center pressure sensor is more sensitive to the first radial resonant mode (0, 1) of the knock pressure oscillation, while the side sensors are more sensitive to the first and second circumferential resonant modes (1, 0) and (2, 0). The knock onset judged by natural flame photography is earlier than that by pressure analysis because the auto-ignition event happens first and induces the subsequent pressure fluctuation. Natural flame luminosity analysis demonstrates that the initial auto-ignition sites only cause weak pressure oscillations, and the instantaneous combustion of the remaining end-gas increases the heat release rate significantly and gives rise to more violent pressure oscillations. Statistically, the maximum amplitude of pressure oscillation follows an exponential relationship with the peak mean flame luminosity. The end-gas resides in the gaps among the flame fronts generated by different spark strategies while the first auto-ignition sites are not evenly distributed in the end-gas zone. This fact gives insights into the local temperature non-uniformity of the end gas zone that affects the spatial distributions of the initial auto-ignition sites in the cylinder.
  • Etch-free additive lithographic fabrication methods for reflective and transmissive micro-optics

    Fu, Qiang; Amata, Hadi; Heidrich, Wolfgang (Optics Express, The Optical Society, 2021-10-22) [Article]
    With the widespread application of micro-optics in a large range of areas, versatile high quality fabrication methods for diffractive optical elements (DOEs) have always been desired by both the research community and by industry. Traditionally, multi-level DOEs are fabricated by a repetitive combination of photolithography and reactive-ion etching (RIE). The optical phase accuracy and micro-surface quality are severely affected by various etching artifacts, e.g., RIE lag, aspect ratio dependent etching rates, and etching artifacts in the RIE steps. Here we propose an alternative way to fabricate DOEs by additively growing multi-level microstructures onto the substrate. Depth accuracy, surface roughness, uniformity and smoothness are easily controlled to high accuracy by a combination of deposition and lift-off, rather than etching. Uniform depths can be realized for both micrometer and millimeter scale features that are simultaneously present in the designs. The grown media can either be used directly as a reflective DOE, or as a master stamp for nanoimprinting refractive designs. We demonstrate the effectiveness of the fabrication methods with representative reflective and transmissive DOEs for imaging and display applications.
  • Optimal Interfacial Band Bending Achieved by Fine Energy Level Tuning in Mixed-Halide Perovskite Solar Cells

    Daboczi, Matyas; Ratnasingham, Sinclair R.; Mohan, Lokeshwari; Pu, Chenfeng; Hamilton, Iain; Chin, Yi-Chun; McLachlan, Martyn A.; Kim, Ji Seon (ACS Energy Letters, American Chemical Society (ACS), 2021-10-21) [Article]
    Most highly efficient perovskite solar cells employ mixed iodide–bromide photoactive layers; however, understanding the beneficial effect of the low (5–15 mol %) bromide content is incomplete. Here, a series of MAPb(I1–xBrx)3 perovskite layers are investigated to understand the origin of the high peak power conversion efficiency (19.2%) observed at small bromide content (0.10 ≤ x ≤ 0.125). For the x = 0.125 perovskite, 200 meV shallower energy levels are revealed, accompanied by a reduced density of trap states and stable tetragonal mixed-halide phase with compressed unit cell. In contrast, the higher bromide content samples (x > 0.125) show deeper energy levels, cubic perovskite crystal structure, and signs of halide segregation. Surface photovoltage measurements unveil an undesirable band bending at the hole transport layer/perovskite interface for MAPbI3 and x > 0.125 mixed-halide layers, which is eliminated for the x = 0.125 perovskite because of its shallower Fermi level, enabling enhanced device performance.

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